3    Water Quality

 

3.1    Introduction

 

This Section provides details of the water quality monitoring to be undertaken by the ET during the construction and operation of the active pits.   Water quality modelling carried out for the EIA indicates that the potential water quality impacts associated with the dredging, backfilling and capping works at the active pits will be within acceptable levels and no adverse water quality impacts are expected.  However, the monitoring programme is designed to verify the predictions of the EIA and ensure compliance with the WQOs. 

 

3.2    Objective

 

The main objective of this component of the study is to determine the impacts on water quality caused by the dredging operations, disposal activities and capping works.  Three separate components of water quality monitoring are necessary. 

 

·                Routine Water Quality Monitoring - conducted to examine the effects of overall operation of the active pits on the level of compliance with the water quality objectives (WQOs) for the NWWCZ;

·                Dissolved Metal Testing - conducted to examine the levels of contaminants in plumes arising from the backfilling operations; and,

·                Water Column Profiling - conducted to examine in situ the effects of dredging, backfilling and capping operations on water quality parameters within the water column.

 

3.3    Hypotheses

 

The impact hypothesis for this work component has been defined based on the predictions from the EIA regarding impacts from the construction of the proposed contaminated mud disposal facilities, the associated contaminated mud disposal operations and the objectives for the study.

Dredging, disposal (backfilling) and capping operations do not result in any exceedances of Northwestern Water Quality Control Zone Water Quality Objectives.

As a consequence of performing three separate tasks for assessing the impacts of dredging works, disposal operations and capping activities on water quality, three null hypotheses will be tested:


Routine Water Quality Monitoring

 

H0      There are no differences in the level of compliance with the appropriate WQOs for the NWWCZ as a result of the overall operation of the active contaminated mud disposal facility.

 

Dissolved Metal Testing

 

H0      There are no differences between the concentrations of contaminants in water samples collected in areas downcurrent of the active contaminated mud disposal facility as compared to areas upcurrent of the facility during backfilling operations. 

 

Water Column Profiling

 

H0      There is no change in the level of compliance with the NWWCZ WQOs of samples taken from the plume arising from dredging, backfilling and capping activities (EIA predicted location).

 

3.4    Sampling Design

 

3.4.1    Routine Water Quality Monitoring

 

The design for this component of the programme allows impacts to water quality as a result of the overall operation of the active facility to be assessed.  Replicate water samples shall be collected at specific sites (fixed locations as indicated on Figures 3.4a and 3.4b) which should be located in three areas at increasing distances from the active facility: near field, mid field and far field/reference.  The samples should be collected at eight times during the year, twice in the dry season, twice during the wet season and twice in each of the two transitional seasons.  The approach will ensure that the impact of temporal changes on the hydrodynamic conditions in the area is considered in the sampling.

 

The number of samples to be collected and the sampling frequency shall be confirmed in advance of the commencement of the disposal activities and agreed with EPD based on the detailed design of the facility.  In principle, reference stations should be located in areas that are free from the influence of sediment plumes resulting from the operation of the facility.  For standardisation purposes, consideration of selecting reference sites at similar locations to the EM&A programmes for the East Sha Chau CMP IV is proposed (Figures 3.4a and 3.4b).  The approach to be adopted for the sampling shall ensure that the impacts on the hydrodynamic conditions in the area resulting from the overall operation of the disposal facility are thoroughly considered.


3.4.2    Dissolved Metal Testing

 

Dissolved metal stations shall be located at fixed stations within the predicted trajectories of the plume.  Samples shall be collected from two dissolved metal stations located on a transect running up-current (flood tide) and five down-current (ebb tide) of the active pits.  The total number of dissolved metal stations and the spacing between sampling stations should be confirmed in advance of the commencement of the disposal activities and agreed with EPD based on the detailed design of the disposal facility.  Making reference to the previous sampling protocol developed for the East Sha Chau CMP monitoring programmes is recommended when devising the sampling protocol for this Project.

 

In order to increase the likelihood of sampling within the plume trajectory and hence increase the ability to detect potential impacts to water quality, the location of the dissolved metal transect should be determined in the field on each sampling occasion depending on the current direction and the location of backfilling at the time of sampling (if backfilling is concurrent).  The position of the dissolved metal stations shall be determined in the field on each sampling occasion depending on two factors: the current direction; and the location of backfilling at the time of sampling (if backfilling is concurrent).  

In principle, water samples shall be collected from stations located on a transect running up-current and down-current of the active pit.  The first down-current station and the first up-current station of the dissolved metal station transect shall be positioned on the edge of the disposal facility at the most appropriate position depending on the factors mentioned above.  The remainder of the up-current or down-current stations shall be positioned at appropriate distances apart from the respective first up-current or down-current station along the transect.

  

The following methodology shall be adopted for monitoring at dissolved metal stations:

 

·         contact the CEDD barge at the start of each survey on every sampling occasion to determine the backfilling schedule for that particular day and to determine the likely location of backfilling at the proposed time of sampling.

·         undertake Water Column Profiling to determine current direction.

·         determine a suitable location for the dissolved metal station transect (with the down-current station should be located on the down current edge, and first up-current station should be located on the up-current edge, of the East of Sha Chau Facility according to the current direction and the position of backfilling at the time of sampling.

·         collect samples from the dissolved metal stations located on a transect running up-current and down-current of the active pit.

 

The above measures shall ensure that water samples are collected from locations directly down-current of the active pits (to determine whether contaminants are being dispersed outside the boundary of the pit), and up-current of the active pit (to determine background concentrations of contaminants).

 

3.4.3    Water Column Profiling

 

A one hour survey shall be conducted at regular intervals (eg monthly) at one station located either in the flood or ebb tide plume depending on the current direction, in order to provide enough time (at least one hour) to identify the optimum sampling location for the dissolved metal testing component.  Water column profiling shall be conducted at mid-depth.

 

3.4.4    Baseline Monitoring

 

Baseline monitoring shall be conducted at all Routine Monitoring Stations in the vicinity of the active facility (Figures 3.4a and 3.4b) and in reference areas (EPD Water Quality Monitoring Stations NM1, 2, 3, 5 and 6) for a period of one month prior to the commencement of marine works in order to gather representative water quality data for the EM&A.

 

The baseline water quality monitoring shall be undertaken three days per week at all stations within a 3 hour window of 1.5 hours before or after mid-flood and mid-ebb tides for four weeks prior to construction works commencing.  The interval between 2 sites of monitoring shall not be less than 36 hours.

Each station will be sampled and measurements will be taken at three depths, 1 m below the sea surface, mid depth and 1 m above the seabed.  Where water depth is less than 6m the mid-depth station may be omitted.  If water depth is less than 3m, only the mid-depth station will be monitored.  Duplicate water samples shall be taken and analyzed.

 

The ET shall be responsible for undertaking the baseline monitoring and submitting the results within 10 working days from the completion of the baseline monitoring work. 

 

Impact Monitoring for Dredging and Capping

 

Impact monitoring during dredging and capping operations of the active pits shall be conducted at mobile stations around the facility where their location is dependent on the location of either the dredging or capping activities.  These mobile stations should be located at an appropriate distance between each other along the up-current or down-current transect for the dredging or capping area.  The positioning of the Impact Monitoring stations shall follow the same rationale as that described above for the Dissolved Metal Stations.  The precise location of the mobile stations shall be determined on each sampling occasion by the contractor conducting the monitoring, after contacting CEDD barge on site to determine the programme and location for dredging and capping.  Sufficient number of sampling stations shall be identified for taking samples to ensure a representative set of sampling data is collected.  The number of samples to be collected and the sampling frequency shall be confirmed in advance of the commencement of the disposal activities and agreed with EPD based on the detailed design of the facility.

 

3.4.5    Statistical Treatment of Data

 

3.4.6    Routine Water Quality Monitoring

 

The hierarchy of sampling design should allow for the application of nested analysis of variance to statistically test any changes or trends in the dataset.  Under the nested design, differences shall be tested between sites in a particular area and between the three areas (ie near field, midfield and farfield).  Once a time series of data has been gathered temporal changes in water quality parameters can be analysed for significant differences.  In addition, the data gathered shall be examined against the water quality objectives for the NWWCZ to determine if the relevant water quality objectives have been exceeded.

 

3.4.7    Dissolved Metal Testing

 

The data gathered during this programme shall be plotted and examined for apparent impacts to water quality or contaminant dispersion in the plumes arising from the backfilling activities.  These data shall be compared with the predictions in the EIA. 

 

3.4.8    Water Column Profiling

 

The data gathered shall be examined against the water quality objectives for the NWWCZ to determine if the relevant water quality objectives have been exceeded.

 

3.5    Use of Data

 

Should increases be detected in the level of contaminants in dissolved metal samples, or exceedances of the NWWCZ WQOs be detected, a review of the other monitoring parameters shall be undertaken.  This shall focus on sampling stations in the vicinity of the water quality stations where increases are detected to see if these can be attributed to contaminant spread from the active pits.  If so, consideration will be given to revising the facility operations plan.

 

3.6    Data Collection Parameters

 

The following suite of parameters shall be measured for each task as detailed below:


3.6.1    Routine Water Quality Monitoring

 

·                Dissolved Oxygen (mg L-1) (in situ and laboratory analysis);

·                pH (in situ and laboratory analysis);

·                Suspended Solids (mg L-1) (laboratory analysis);

·                Ammonia (mg L-1) (laboratory analysis);

·                Nutrients (TIN mg L-1) (laboratory analysis);

·                5-Day Biochemical Oxygen Demand (BOD) (mg L-1)(laboratory analysis); and

·                Turbidity (NTU) (in situ and laboratory analysis).

 

3.6.2    Dissolved Metals Contaminant Testing

 

The measurements listed above for the routine water quality monitoring along with the following inorganic contaminants shall be tested:

 

·                Cadmium;

·                Chromium;

·                Copper;

·                Lead;

·                Mercury;

·                Nickel;

·                Silver;

·                Zinc; and

·                Arsenic.

 

3.6.3    Water Column Profiling

 

·                Salinity (ppt) (in situ);

·                Dissolved Oxygen (mg L-1) (in situ and laboratory analysis);

·                Suspended Solids (mg L-1)(laboratory analysis);

·                Turbidity (FTU) (in situ);

·                Temperature (oC) (in situ); and

·                Current Velocity and Direction (m s-1) (in situ).


3.7    Sampling Procedure

 

The position of the survey vessel shall be positioned to within 3 m of the designated coordinates at each monitoring station using a differential Global Positional System (GPS).  In situ water quality (salinity, temperature, DO and SS) and, current velocity and direction, shall be conducted from the survey vessel using the equipment recommended in Section 3.8.  In order to ensure the reliability and quality of the data, the measuring instrument shall be calibrated prior to each sampling cruise and the probe of the measuring instrument shall be maintained at a suitable distance from the seabed to avoid re-suspension of bottom sediments from skewing the results. 

Water quality profiling shall be conducted continuously for a one-hour period from a fixed point.  After deployment, the probe of the measuring equipment shall be allowed to equilibrate with the surrounding seawater for approximately 30 seconds.  Subsequently, average readings shall be taken every few seconds to minimise sampling noise arising from the sensitivity of the equipment.  To further calibrate the in-situ turbidity measurements, water samples shall be collected for calibrating and converting to turbidity measurements in the laboratory.  In addition to in-situ water quality monitoring, water samples shall be collected in a water sampler at mid-depth.  Samples shall be stored in sealed sampling bottles and chilled, and on completion of the survey shall be transported to the laboratory for immediate analysis.  Samples not for immediate analysis shall be stored at 4 ± 2°C.

 

3.8    Equipment

 

The following equipment shall be supplied and used by the contractor for the water quality monitoring:

 

·            Positioning Device - A Global Positioning System (GPS) shall be used during monitoring to ensure the accurate recording of the position of the monitoring vessel before taking measurements.  The GPS shall be calibrated daily before each survey period or results reported.

·            Dissolved Oxygen and Temperature Measuring Equipment - The instrument shall be a portable, weatherproof dissolved oxygen measuring instrument complete with cable, sensor, comprehensive operation manuals, and shall be operable from a DC power source.  It shall be capable of measuring:  dissolved oxygen levels in the range of 0 - 20 mg L-1 and 0 - 200% saturation; and a temperature of 0 - 45 degrees Celsius.

 

It shall have a membrane electrode with automatic temperature compensation complete with a cable of not less than 20 m in length.  Sufficient stocks of spare electrodes and cables shall be available for replacement where necessary (for example, YSI model 59 metre, YSI 5739 probe, YSI 5795A submersible stirrer with reel and cable or an approved similar instrument).

 

·            Turbidity Measurement Equipment - Turbidity within the water shall be measured in situ by the nephelometric method.  The instrument shall be a portable, weatherproof turbidity-measuring unit complete with cable, sensor and comprehensive operation manuals.  The equipment shall be operated from a DC power source, it shall have a photoelectric sensor capable of measuring turbidity between 0 - 1000 NTU and shall be complete with a cable with at least 20 m in length (Hach 2100P or an approved similar instrument).

 

·            Salinity Measurement Instrument - A portable salinometer capable of measuring salinity in the range of 0 - 40 ppt shall be provided for measuring salinity of the water at each monitoring location.

 

 

·            Suspended Solid Measurement Equipment - A water sampler (eg Kahlsico Water Sampler), which is a PVC cylinder (capacity not less than 2 litres) which can be effectively sealed with latex cups at both ends, shall be used for sampling.  The sampler shall have a positive latching system to keep it open and prevent premature closure until released by a messenger when the sampler is at the selected water depth.  Water samples for suspended solids measurement shall be collected in high density polythene bottles, packed in ice (cooled to 4oC without being frozen), and delivered to the laboratory in the same day as the samples were collected.

 

·            Water Depth Gauge - A portable, battery-operated echo sounder (Seafarer 700 or a similar approved instrument) shall be used for the determination of water depth at each designated monitoring station.  This unit shall either be hand-held or affixed to the bottom of the work boat if the same vessel is to be used throughout the monitoring programme.

 

 

·            Water Sampling Equipment - A water sampler, consisting of a transparent PVC or glass cylinder of not less than two litres which can be effectively sealed with cups at both ends, shall be used (Kahlsico Water Sampler 13SWB203 or an approved similar instrument).  The water sampler shall have a positive latching system to keep it open and prevent premature closure until released by a messenger when the sampler is at the selected water depth.

 

·            Current Velocity Measuring Equipment – A Valeport 108 MKIII current meter or a similar approved instrument shall be used for measuring current velocity and direction.  The instrument shall be calibrated before taking data.

 

 

3.9    Laboratory Procedures

 

Using chain of custody forms, collected water samples shall be transferred directly to laboratory for immediate processing of dissolved oxygen, pH, suspended solids, ammonia, nutrients, BOD5 and turbidity.  Water samples shall be analysed for pH and BOD within 4 hours of their arrival at the laboratory.  All other parameters shall be analysed within 48 hours of arrival.  During this period samples shall be held at 4 ± 2ºC.  Prior to subjecting the sample to metals analysis, samples shall be filtered to remove solids and colloidal matter.  Filtration shall be accomplished using acid washed, single-use 0.45 micron membrane filters within a maximum of 8 hours from sample collection.  Where necessary, samples shall undergo further preparation involving preconcentration which allows lower method detection limits to be achieved and removes some of the possible sources of interference.

 

3.10    QA/QC

 

3.10.1    Field Logs

 

Field logs shall be maintained for all survey work, noting the date of the survey, equipment used, survey manager and a record of all activities and observations.  Field logs shall be retained for the duration of the Project and archived on completion.

In-situ measured data shall be digitally recorded from the instruments and converted into Microsoft Excel format, or manually noted.  Both disc copy and hard copy shall be retained for the file records.  Any deviation from the standard procedure shall be noted in the log and the reason for the deviation recorded.  In addition, field logs shall contain notes of events or activities in the vicinity of the monitoring location which might give rise to anomalous data being recorded.

 

3.10.2    Sampling

 

The sampling, collection, storage and identification procedures are described in Section 3.7 of this Manual and the person who conducts the sampling shall record all data from in-situ testing and from any analysis carried out on the boat in a Field Log.  All samples shall be identified with a unique date/time/location/depth/sample-type code which shall be attached to the sample container or written in indelible ink directly on the container.  In order to avoid contamination of the samples, all containers shall be new and unused and of analytical grade quality. Sources of contamination shall be isolated from the working area (for example, vessel fuel and exhaust fames) and any sample contaminated by local material (such as printed circuit boards) shall be discarded and the sampling repeated.  Low level metal analysis in seawater is easily contaminated through inappropriate handling and sampling techniques.  Site staff involved in seawater sample collection intended for dissolved metal analysis shall ensure that they wear non-contaminating disposable gloves if they have previously been operating or have handled metallic equipment.

 

3.10.3    Measurement Procedures

 

All in-situ monitoring instruments shall be checked, calibrated and certified and subsequently re-calibrated at 3 monthly intervals throughout all stages of the water quality monitoring, or as required by the manufactures specification.  Certificate(s) of Calibration specifying the instrument shall be attached to the monitoring reports.

 

3.10.4    Transport of Samples

 

All samples transferred from one sub-contractor to another shall be accompanied by Chain of Custody (COC) forms.  Any missing or damaged samples require notification to ET Leader following logging in the laboratory QA system.  The number of samples, the parameters to be tested and the time of delivery should be clearly stated on the COC forms to ensure that samples are analysed for the correct parameters and suitable time is provided to the analytical laboratory for provision of resources required in the analyses.

 

3.10.5    Laboratory Procedures

 

For details of the contaminants to be tested, the methods to be used, the accreditation status of laboratory analytical methods, instruments and procedures to be used, sample preparation information, method detection limits (MDLs), QA/QC protocols and turnaround times, contractor should refer to the previous monitoring programme for the ESC CMPIV ([1]) ([2]). 

The analytical techniques to be adopted for this Project must conform to HOKLAS (or similar overseas) accreditation. 

 

3.10.6    Data Quality Objectives

 

Data Quality Objectives (DQOs) have been developed in the previous monitoring programme for ESC CMPIV ([3]) ([4]) to address precision, accuracy and analyte recovery.  The contractor is recommended to follow the DQOs developed for data analysis. 

Inorganic Analyses

Details of quality control specifications for inorganic testing should be included in the updated EM&A Manual prior to commencement of disposal activities.

 

Precision

 

Duplicates (1 in every 10 samples) shall be used to monitoring the precision of the analysis.  Results should be flagged for reference when:

·                In water samples, for metals with a concentration >4x MDL, the duplicate results have more than a 15% RPD

·                For all analytes with concentration <4x MDL, the duplicate results shall be reported as analysed and no bounds should be quoted

 

Accuracy

 

Standard and certified reference material (CRM) shall be used to monitor accuracy and precision within and between batches:  Results should be flagged for reference if:

 

·                The variation of the standard from its true value is more than ± 15% (for mercury: ± 20%).

 

Recovery

 

Post digest spikes shall be used to determined the recovery of determinants in complex sample matrices.  Results should be rejected if:

 

·                Spike recoveries are more than ± 25% from the theoretical recovery for water samples.  An exceptional case would be if the sample concentration is greater than four times the spike value, the spike may be disregarded.

 

3.11    Water Quality Compliance and Event & Action Plan

 

Water quality monitoring will be evaluated against Action and Limit Levels.  The key assessment parameters are dissolved oxygen and suspended sediment and thus Action and Limit Levels based on the assessment criteria are identified for these.  However turbidity can also provide valuable instantaneous information on water quality and thus an Action Limit is also recommended for this parameter to facilitate quick responsive action in the event of any apparent unacceptable deterioration attributable to the works.  The baseline data will be taken into account in setting the Action and Limit Levels, however, the rationale are shown in Table 3.1

Action and Limit levels are used to determine whether operational modifications are necessary to mitigate impacts to water quality.  In the event that the levels are exceeded, appropriate actions in Event and Action Plan (Table 3.2) should be undertaken. 


Table 3.1    Action and Limit Levels for Water Quality

Parameter

Action Level

Limit Level

Dissolved Oxygen

 

 

Surface and Middle

Depth Averaged

The depth average of the impact station readings are <5%ile of baseline data

 

and

 

significantly less than the reference stations mean DO (at the same tide of the same day)

The average of the impact station readings are <4mg/L

 

and

 

Significantly less than the reference stations mean DO (at the same tide of the same day)

Bottom

The average of the impact station readings are <5%ile of baseline data

 

and

 

Significantly less than the reference stations mean DO (at the same tide of the same day)

The average of the impact station readings are <2mg/L

 

and

 

Significantly less than the reference stations mean DO (at the same tide of the same day)

Suspended Solids

 

 

Depth Averaged

The depth average of the impact station readings are >95%ile of baseline data

 

and

 

120% or more of the reference stations SS (at the same tide of the same day)

The depth average of the impact station readings are >99%ile of baseline data

 

and

 

130% or more of the reference stations SS (at the same tide of the same day)

Turbidity

 

 

Depth Averaged

The depth average of the impact station readings are >95%ile of baseline data

 

and

 

120% or more of the reference stations turbidity (at the same tide of the same day)

The depth average of the impact station readings are >99% of baseline data

 

and

 

130% or more of the reference stations turbidity (at the same tide of the same day)

 


Table 3.2    Water Quality Event and Action Plan

Event

Environmental Team (ET)

Contractor

Action Level

 

 

Exceedance for one sample

·          Repeat in-situ measurement to confirm findings;

·          Identify the source(s) of impact;

·          Inform contractor and contractor informs CEDD, EPD and AFCD and confirm notification of the non-compliance in writing;

·          Check monitoring data;

·          Discuss potential mitigation measures if exceedance is attributed to the works with contractor.

·          Discuss potential mitigation measures with ET and agree on mitigation measures to be implemented if exceedance is attributed to the works;

·          Ensure mitigation measures are implemented;

·          Assess the effectiveness of the implemented mitigation measures.

Limit Level

 

 

Limit level for one occasion

·          Repeat in-situ measurement to confirm findings;

·          Identify source(s) of impact;

·          Inform contractor and contractor informs CEDD, EPD and AFCD;

·          Discuss further mitigation measures if exceedance is attributed to the works with contractor;

·          Increase the monitoring frequency to daily if exceedance is attributed to the works until no exceedance of the Limit Level.

·          Critical review of working methods;

·          Check plant, equipment and working methods;

·          Discuss further mitigation measures with ET to be implemented if exceedance is attributed to the works;

·          Ensure mitigation measures are being implemented;

·          Assess the effectiveness of the implemented mitigation measures.

 

 

 

Limit Level exceeded on two or more occasions

·          Identify source(s) of impact;

·          Inform contractor and contractor informs, CEDD, EPD and AFCD.

 

·          If exceedance is attributed to the works consider and if necessary reduce works until no exceedance of Limit Level.

 

 

 

Impacts attributable to works

·          Inform contractor and contractor informs, CEDD, EPD and AFCD.

 

·          Comprehensive review of works;

·          Reduce works; and

·          Suspension of works.

 

 



([1])          ERM (2001) Environmental Monitoring and Audit for Contaminated Mud Pit IV at East Sha Chau:  Monitoring and Audit Manual.  Submitted to CED, February 2001.

([2])          Mouchel (2001)  Consultancy for Environmental Monitoring and Audit for Contaminated Mud Pit IV at East Sha Chau (2000-2005):  Monitoring and Audit Manual.  Submitted to CED, May 2001.

([3])          ERM (2001)  Op cit.

([4])          Mouchel (2001)  Op cit.