E1                       Characteristics of Bioheating Oil

E1.1                 Chemical Composition

Bioheating oil is the residue out of the biodiesel distillation.  It consists of:

40-80 %wt                  Methyl ester

1-30 % wt                    Dimere Methyl ester (depending on polymers from Used Cooking Oil)

1- 25 % wt                  Mono,-Di- and Triglycerides

1- 5 % wt                    Fatty acids

1- 5 % wt                    Organic components from feedstock (colour, non saponifiable)

0.1 – 0.4 % wt            Ash

max. 2,000 ppm        Sulphur (depending on feedstock)

E1.2                  Physical properties:

General information

 

·       Physical condition

·       colour

·       odour

liquid at temperatures above 60 to 80 oC

dark brown or black

characteristic, depending on feedstock

Flashpoint

about 170oC

Inflammation temperature

about 400oC

Explosion hazard

at ambient temperature the product does not represent an explosion hazard

Density at 40%.

approx. 914 kg/m3 to 935 kg/m3

Density at 80%

approx. 885 kg/m3 to 907 kg/m3

Viscosity at 40%

50mm2/s to 500 mm2/s

Viscosity at 80%

13mm2/s to 50 mm2/s

Flammability

 

at ambient temperature auto-ignition of the product is not possible

Electrical conductivity

0.2 µS/cm

Dielectricity constant

3.9

E1.3                  Comparison of Biodiesel with Bioheating Oil

 

Unit

Biodiesel

Bioheating Oil

 

 

Min.

Max.

Min.

Max.

Ester-content

% (m/m)

96.5

 

40

80

Density at 15oC

kg/m3

860

900

914

(40oC)

935

(40oC)

Viscosity at 40oC

Mm2/s

3.50

5.00

50

500

Flash point

oC

120

-

187

-

Sulphur content

mg/kg

-

10

58

2,000

Linolenic acid – methylester

% (m/m)

-

12.0

-

12.0

Methanol content

% (m/m)

-

0.20

0.0

0.05

Monoglyceride content

% (m/m)

-

0.80

1-25%

Diglyceride content

% (m/m)

-

0.20

1-25%

Triglyceride content

% (m/m)

-

0.20

1-25%

Free glycerol

% (m/m)

-

0.200

0

0.02

Total glycerol

% (m/m)

-

0.25

2.38

5.83