Ozone Layer Protection and You
Content
- What is meant by "ozone hole"?
- Why it concerns you?
- What causes this phenomenon?
- What are these ozone depleting substances (ODS) used for?
- Can we get rid of the ODS?
- What are the international efforts in saving the ozone Layer?
- How does Hong Kong control the ODS?
- What is the Ozone Layer Protection (Products Containing Scheduled Substances) (Import Banning) Regulation about?
- What is the Ozone Layer Protection (Controlled Refrigerants) Regulation about?
- How can I help to protect the ozone layer?
- Further Information
- Schedule
(1) What is meant by "ozone hole"?
Since about 1975, scientists have detected a severe drop in ozone concentration in the layer over the Antarctica each spring. The situation then reached an alarming scale in 1987 when an international expedition found that half of the Antarctica's ozone have disappeared over a region twice the size of the United States, creating an enormous "hole" in the ozone layer. Concentrations of ozone fell by as much as 50% of the norm at altitude of 18 km. At mid-latitudes in the Northern Hemisphere, up to 3% decrease in ozone concentration was also observed.
Acknowledgement:
Permission to use the image of "ozone hole" from the Ozone Processing Team, Goddard Space Flight Centre, NASA, and the ozone depleting illustration schematic from the Centre for Atmospheric Science, Chemistry Dept., University of Cambridge ("Ozone Hole Tour" website address,http://www.atm.ch.cam.ac.uk/tour/) is gratefully acknowledged.
(2) Why it concerns you?
The ozone molecules form a protective layer which extends from about 16 km to 50 km up above the earth at low latitudes, and from about 8 km to 50 km at high latitudes. The ozone molecules absorb the sun's ultra violet radiation (UV) which will be harmful to us if it reaches the earth surface. With more UV radiation reaching the earth surface due to ozone depletion, human health and the environment will be adversely affected. The most significant effects will be the increased incidence of skin cancer, eye cataracts, damage to the human immune system and to the ecology of the earth.
(3) What causes this phenomenon?
Scientists have reached consensus that ozone depletion in the stratosphere is caused by ozone depleting chemicals. These chemicals contain chlorine or bromine atom with inherent chemical stability and have long lifetime in the atmosphere, in the range of 40 to 150 years. These chemicals and other trace gases drift up into the stratosphere and become involved in chlorine-releasing reactions. The chlorine atoms then react with the ozone molecules in the presence of sunlight and destroy the ozone molecules. Just one chlorofluorocarbon molecule can destroy tens of thousands of ozone molecules.
These ozone-depleting chemicals are extensively used man-made chemicals including the followings: -
-
chlorofluorocarbons (CFCs);
-
halons;
-
1,1,1-trichloroethane (methyl chloroform);
-
carbon tetrachloride;
-
methyl bromide;
-
hydrobromofluorocarbons (HBFCs);
-
hydrochlorofluorocarbons (HCFCs); and
-
bromochloromethane (BCM).
Ozone depleting substances destroy the ozone molecules and allow more UV radiation reaching the earth
(4) What are these ozone depleting substances (ODS) used for?
The following are the common usage of CFCs and HCFCs :
- CFC-11, CFC-12 and HCFC-22 are used as refrigerant in domestic air-conditioners and refrigerators as well as retail store refrigeration systems, chillers and air-conditioners.
- CFC-11 and CFC-12 are used as propellants for aerosol sprays such as hair mousses and household cleaning products.
- CFC-11 and CFC-12 are also used as blowing agents in the manufacture of foams for home furnishing, insulation and packaging. Some plastics may be shaped using CFCs, e.g. egg cartons, cups and cartons used in fast food operations. Rigid or semi-rigid foams are also used as thermal or sound insulation in refrigeration equipment, buildings and automobiles.
- CFC-113 is a solvent for cleaning electronic circuit boards and computer components.
- solvent for cleaning electronic circuit boards and metal work such as watches and clockworks.
- thinner such as that for correction fluid.
- cleaning agent in the textile industry (dry cleaning).
Carbon tetrachloride is used as a cleaning agent in textile and electronics industries.
(5) Can we get rid of the ODS?
There has been considerable progress in finding non-ozone-depleting substitutes for ODS in the last few years. Substitutes for air-conditioning and refrigeration applications are now available, such as that HCFC-22 can be replaced by HFC-410A, CFC-12 can be replaced by HFC-134a. There are also emerging markets for "drop-in" replacement for HCFCs and halons.
Alternative products or processes can be used in some cases including the following:
-
alternative insulating materials;
-
substitute food containers such as hydrocarbon blown polystyrene, plastic film wrap and bags;
-
alternative packaging materials such as plastic film bubble wraps; and
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air-conditioning and refrigeration plants operating on non-HCFC refrigerants.
HCFCs solvents can be substituted in some applications. For instance, petroleum solvents can be selected as a replacement for CFC-113 or 1,1,1-trichloroethane in cleaning applications. Aqueous cleaning, or even no-clean technology, are also alternative processes that can be used by the electronics industry.
Many household and personal aerosol products, e.g. paint sprays and insecticides, now use hydrocarbons (e.g. propane and butane) as propellants instead of HCFCs or CFCs.
(6) What are the international efforts in saving the ozone layer?
In September 1987, an international treaty aimed at saving the Earth's ozone layer, known as the Montreal Protocol on Substances that Deplete the Ozone Layer, was signed in Montreal, Canada. The Protocol requires the phasing out of the ODS in accordance with agreed schedules. Following lists the ODS phasing out schedules applicable to Hong Kong:
Halons |
Import for local consumption banned by 1.1.1994
|
CFCs Carbon Tetrachloride 1,1,1-Trichloroethane HBFCs |
Import for local consumption banned by 1.1.1996
|
Methyl Bromide |
Import restricted to local quarantine and pre-shipment applications only by 1.1.1995
|
HCFCs |
Freeze consumption at base level starting 1.1.1996
35% reduction of import for local consumption by 1.1.2004
75% reduction of import for local consumption by 1.1.2010
90% reduction of import for local consumption by 1.1.2015
100% reduction of import for local consumption by 1.1.2020[1]
[1] Allow 0.5% of the 1989 base level for servicing of refrigeration and air-conditioning equipment in the period 2020-2029.
|
BCM |
Import for local consumption banned by 1.10.2009
|
(7)How does Hong Kong control the ODS?
To fulfil Hong Kong Special Administrative Region's international obligations under the 1985 Vienna Convention for the Protection of the Ozone Layer and the 1987 Montreal Protocol on Substances that Deplete the Ozone Layer, the Ozone Layer Protection Ordinance (CAP. 403)was enacted in July 1989 to provide a statutory framework for the control of ozone depleting substances. The chemicals under control are referred to as "scheduled substances" in the Ordinance (Please see Session 12 - Schedule). The Ordinance prohibits the manufacturing of such substances and imposes controls on the import and export of these substances through registration and licensing provisions. The following is a summary of the related control:
Measures
|
Commencement Date
|
---|---|
Control of import and export of scheduled substances |
1.7.1989
|
Banning of import for local consumption of halons |
1.1.1994
|
Licensing of import of methyl bromide strictly for local quarantine and pre-shipment applications |
1.1.1995
|
Banning of import for local consumption of CFCs, 1,1,1-trichloroethane,carbon tetrachloride and HBFCs |
1.1.1996 |
Licensing of import of HCFCs for local consumption |
1.1.1996
|
Banning of import for local consumption of BCM |
1.10.2009
|
Under the registration and licensing system, persons who wish to import or export any of the ODS must:
-
first register with the Trade and Industry Department,
-
apply for a licence from the Trade and Industry Department on each occasion, and/or
-
possess the quota to import the HCFC for local consumption .
In 1993, two pieces of legislation were introduced under the Ozone Layer Protection Ordinance:
-
The Ozone Layer Protection (Products Containing Scheduled Substances) (Import Banning) Regulation
-
The Ozone Layer Protection (Controlled Refrigerants) Regulation
Copies of the Ozone Layer Protection Ordinance and subsidiary regulations are on sale at the Government Publications Centre. Also, they can be browsed from the web site of Bilingual Laws Information System at http://www.elegislation.gov.hk.
(8) What is the Ozone Layer Protection (Products Containing Scheduled Substances) (Import Banning)(Amendment) Regulation about?
This Regulation prohibits the import of controlled products containing HCFCs, CFCs and halons, etc.:
-
an air-conditioner or heat pump designed to cool the driver's or passengers' compartment of a motor vehicle (whether or not installed in the motor vehicle);
-
refrigeration equipment or air-conditioning or heat pump equipment (whether for domestic or commercial use);
-
an aerosol product including those containing a pharmaceutical product or medicine as defined in section 2 of the Pharmacy and Poisons Ordinance (Cap. 138) ;;
-
insulation panel, insulation board or insulation pipe cover;
-
a pre-polymer;
-
portable fire extinguishers containing CFCs, halons, HCFCs or BCM.
(9) What is the Ozone Layer Protection (Controlled Refrigerants) Regulation about?
This Regulation prohibits any intended release of controlled refrigerants from motor vehicle air-conditioners or refrigeration equipment containing more than 50 kg of refrigerant charge into the atmosphere, and to conserve the controlled refrigerants through the use of approved recycling and recovery equipment.
For enforcement and monitoring purposes, owners or operators of industrial/commercial refrigeration systems, as well as proprietors of garages, shall be required to keep records on relevant repair services and the amount of CFC-based refrigerants consumed. Proprietors of vehicle scrap-yards shall also be required to keep records on the number of motor vehicle air conditioners decommissioned as well as the amount of CFC-based refrigerants recovered from the decommissioned air conditioners.
(10) How can I help to protect the ozone layer?
While the vast majority of ODS usage is either industrial or commercial, individuals can help in the following ways:
- Buy air-conditioning and refrigeration equipment that do not use HCFCs as refrigerant.
- Buy aerosol products that do not use HCFCs or CFCs as propellants.
-
Conduct regular inspection and maintenance of air-conditioning and refrigeration appliances to prevent and minimize refrigerant leakage.
- For existing air-conditioning and refrigeration appliances that operate on HCFCs or CFCs, the refrigerant should be recovered or recycled whenever an overhaul of equipment is to be carried out. Replacing or retrofitting such equipment to operate on non-HCFCs refrigerant should also be considered.
- When motor vehicle air-conditioners need servicing, make sure that the refrigerants are properly recovered and recycled instead of being vented to the atmosphere.
(11) FURTHER INFORMATION
Enquiries concerning the Ozone Layer Protection Ordinance and any other general information on the registration and licensing provisions may be made to the Air Science and Modelling Group of Environmental Protection Department at the following address:
Address | Telephone | Facsimile |
---|---|---|
33/F, Revenue Tower, | 2594 6593 | 2827 8040 |
5 Gloucester Road, | 2594 6225 | |
Wan Chai, Hong Kong |
Enquiries regarding the application for registration and import or export licences may be made to the Non-textiles Licensing Unit of Trade and Industry Department at the following address:
Address | Telephone | Facsimile |
---|---|---|
Room 1309, 13/F, Trade and Industry Tower, 3 Concorde Road, Kowloon City, Hong Kong. |
2398 5560
|
2380 8504 |
Website: www.tid.gov.hk/english/import_export/nontextiles/nt_ozone/nt_ozone.html |
(12) SCHEDULE
Scheduled Substances
A substance listed in this Schedule includes, except as otherwise stated, the substance's isomers.
PART 1
Chlorofluorocarbons (CFCs)
Chemical Name |
Common Name |
|
CFCl3 |
Trichlorofluoromethane |
CFC-11 |
CF2Cl2 |
Dichlorodifluoromethane |
CFC-12 |
C2F3Cl3 |
Trichlorotrifluoroethane |
CFC-113 |
C2F4Cl2 |
Dichlorotetrafluoroethane |
CFC-114 |
C2F5Cl |
Chloropentafluoroethane |
CFC-115 |
PART 2
Halons
Chemical Name |
Common Name |
|
CF2BrCl |
Bromochlordifluoromethane |
halon 1211 |
CF3Br |
Bromotrifluoromethane |
halon 1301 |
C2F4Br2 |
Dibromotetrafluoroethane |
halon 2402 |
PART 3
Other Fully Halogenated Chlorofluorocarbons
Chemical Name |
Common Name |
|
CF3Cl |
Chlorotrifluoromethane |
CFC-13 |
C2FCl5 |
Pentachlorofluoroethane |
CFC-111 |
C2F2Cl4 |
Tetrachlorodifluoroethane |
CFC-112 |
C3FCl7 |
Heptachlorofluoropropane |
CFC-211 |
C3F2Cl6 |
Hexachlorodifluoropropane |
CFC-212 |
C3F3Cl5 |
Pentachlorotrifluoropropane |
CFC-213 |
C3F4Cl4 |
Tetrachlorotetrafluoropropane |
CFC-214 |
C3F5Cl3 |
Trichloropentafluoropropane |
CFC-215 |
C3F6Cl2 |
Dichlorohexafluoropropane |
CFC-216 |
C3F7Cl |
Chloroheptafluoropropane |
CFC-217 |
PART 4
Methyl Chloroform
Chemical Name |
Common Name |
|
C2H3Cl3 |
1,1,1-Trichloroethane |
Methyl Chloroform |
PART 5
Carbon Tetrachloride
Chemical Name |
Common Name |
|
CCl4 |
Tetrachloromethane |
Carbon Tetrachloride |
PART 6
Methyl Bromide
Chemical Name |
Common Name |
|
CH3Br |
Bromomethane |
Methyl Bromide |
PART 7
Hydrobromofluorocarbons (HBFCs)
Chemical Name |
Common Name |
|
CHFBr2 |
||
CHF2Br |
Bromodifluoromethane |
HBFC-22B1 |
CH2FBr |
Bromofluoromethane |
--- |
C2HFBr4 |
Tetrabromofluoroethane |
--- |
C2HF2Br3 |
Tribromodifluoroethane |
--- |
C2HF3Br2 |
Dibromotrifluoroethane |
--- |
C2HF4Br |
Bromotetrafluoroethane |
--- |
C2H2FBr3 |
Tribromofluoroethane |
--- |
C2H2F2Br2 |
Dibromodifluoroethane |
--- |
C2H2F3Br |
Bromotrifluoroethane |
--- |
C2H3FBr2 |
Dibromofluoroethane |
--- |
C2H3F2Br |
Bromodifluoroethane |
--- |
C2H4FBr |
Bromofluoroethane |
--- |
C3HFBr6 |
Hexabromofluoropropane |
--- |
C3HF2Br5 |
Pentabromodifluoropropane |
--- |
C3HF3Br4 |
Tetrabromotrifluoropropane |
--- |
C3HF4Br3 |
Tribromotetrafluoropropane |
--- |
C3HF5Br2 |
Dibromopentafluoropropane |
--- |
C3HF6Br |
Bromohexafluoropropane |
--- |
C3H2FBr5 |
Pentabromofluoropropane |
--- |
C3H2F2Br4 |
Tetrabromodifluoropropane |
--- |
C3H2F3Br3 |
Tribromotrifluoropropane |
--- |
C3H2F4Br2 |
Dibromotetrafluoropropane |
--- |
C3H2F5Br |
Bromopentafluoropropane |
--- |
C3H3FBr4 |
Tetrabromofluoropropane |
--- |
C3H3F2Br3 |
Tribromodifluoropropane |
--- |
C3H3F3Br2 |
Dibromotrifluoropropane |
--- |
C3H3F4Br |
Bromotetrafluoropropane |
--- |
C3H4FBr3 |
Tribromofluoropropane |
--- |
C3H4F2Br2 |
Dibromodifluoropropane |
--- |
C3H4F3Br |
Bromotrifluoropropane |
--- |
C3H5FBr2 |
Dibromofluoropropane |
--- |
C3H5F2Br |
Bromodifluoropropane |
--- |
C3H6FBr |
Bromofluoropropane |
--- |
PART 8
Hydrochlorofluorocarbons (HCFCs)
Chemical Name |
Common Name |
|
CHFCl2 |
Dichlorofluoromethane |
HCFC-21 |
CHF2Cl |
Chlorodifluoromethane |
HCFC-22 |
CH2FCl |
Chlorofluoromethane |
HCFC-31 |
C2HFCl4 |
Tetrachlorofluoroethane |
HCFC-121 |
C2HF2Cl3 |
Trichlorodifluoroethane |
HCFC-122 |
C2HF3Cl2 |
Dichlorotrifluoroethane |
HCFC-123 |
C2HF4Cl |
Chlorotetrafluoroethane |
HCFC-124 |
C2H2FCl3 |
Trichlorofluoroethane |
HCFC-131 |
C2H2F2Cl2 |
Dichlorodifluoroethane |
HCFC-132 |
C2H2F3Cl |
Chlorotrifluoroethane |
HCFC-133 |
C2H3FCl2 |
Dichlorofluoroethane |
HCFC-141 |
C2H3F2Cl |
Chlorodifluoroethane |
HCFC-142 |
C2H4FCl |
Chlorofluoroethane |
HCFC-151 |
C3HFCl6 |
Hexachlorofluoropropane |
HCFC-221 |
C3HF2Cl5 |
Pentachlorodifluoropropane |
HCFC-222 |
C3HF3Cl4 |
Tetrachlorotrifluoropropane |
HCFC-223 |
C3HF4Cl3 |
Trichlorotetrafluoropropane |
HCFC-224 |
C3HF5Cl2 |
Dichloropentafluoropropane |
HCFC-225 |
C3HF6Cl |
Chlorohexafluoropropane |
HCFC-226 |
C3H2FCl5 |
Pentachlorofluoropropane |
HCFC-231 |
C3H2F2Cl4 |
Tetrachlorodifluoropropane |
HCFC-232 |
C3H2F3Cl3 |
Trichlorotrifluoropropane |
HCFC-233 |
C3H2F4Cl2 |
Dichlorotetrafluoropropane |
HCFC-234 |
C3H2F5Cl |
Chloropentafluoropropane |
HCFC-235 |
C3H3FCl4 |
Tetrachlorofluoropropane |
HCFC-241 |
C3H3F2Cl3 |
Trichlorodifluoropropane |
HCFC-242 |
C3H3F3Cl2 |
Dichlorotrifluoropropane |
HCFC-243 |
C3H3F4Cl |
Chlorotetrafluoropropane |
HCFC-244 |
C3H4FCl3 |
Trichlorofluoropropane |
HCFC-251 |
C3H4F2Cl2 |
Dichlorodifluoropropane |
HCFC-252 |
C3H4F3Cl |
Chlorotrifluoropropane |
HCFC-253 |
C3H5FCl2 |
Dichlorofluoropropane |
HCFC-261 |
C3H5F2Cl |
Chlorodifluoropropane |
HCFC-262 |
C3H6FCl |
Chlorofluoropropane |
HCFC-271 |
PART 9
Bromochloromethane (BCM)
Chemical Name |
Common Name |
|
CH2BrCl |
Bromochloromethane |
--- |