6.                         BIOGAS RISK ASSESSMENT

6.1                      Introduction

6.1.1                 Since it is a current policy to leave mud in place whenever feasible, to minimise the amount of dredging, most of the reclamation for both the Full Reclamation or Miminised Reclamation options will take place over existing marine sediment.  It is proposed that reclamation would involve the placement of marine sand and/or public dump on top of marine sediments, with the installation of vertical band drains to accelerate consolidation.  Dredging would only occur for the seawall foundation.

6.1.2                 Some of this marine sediment contains levels of organic matter.  When marine sediments rich in organic matter are covered over by reclamation fill, anaerobic degradation of the organic matter in the sediments would generate biogas (methane) which could pose a potential risk to the overlying future landuse.  The issue of methane risk is not a requirement in the TM on EIA Process but warrants investigation, as required in the Study Brief.  The potential gas emission from the proposed Full Reclamation and Minimized Reclamation options at Yau Tong Bay is assessed in the following section.

6.2                      Assessment Methodology and Criteria

Field Sampling and Laboratory Analysis

6.2.1                 Sediment samples were collected at nine vibrocore locations as indicated in Figure 5.1.  Four of these locations were along the proposed seawall and bored pile wall for the Full Reclamation option and five were within the boundary of the proposed reclamation area (Full or Minimized Reclamation options).  Depending on the depth of mud at each location, on average five to seven sediment samples were collected throughout the strata.  The collected samples were packed in ice and transported to MateriaLab for analysis of Total Organic Carbon (TOC) content and Sediment Oxygen Demand (SOD).

6.2.2                 As the marine sediment along the proposed seawall and bored pile wall will be dredged or excavated, the potential impact of gas emissions would be mainly from the reclamation where marine sediment will be left in-situ.  Thus TOC and SOD levels in the sediment samples collected from the five vibrocores within the boundary of the reclamation area are used for the assessment of methane hazard for the Full Reclamation and Minimized Reclamation.  Relevant sample locations and the results are presented in Table 6.1.  Sediment samples in the top 5 m of sediment at each vibrocore location were selected because of their comparatively higher levels of TOC and SOD.  The highest SOD levels were measured within the top 3m of sediment at vibrocore locations V6 and V8A, and within the top 2m of sediment at vibrocore locations V7 and V9B.

 


Table 6.1  Sample Locations and Levels of Total Organic Carbon and Sediment Oxygen Demand

 

Location

Sample Depth

(m)

Moisture

(% w/w)

TOC

(% dry wt)

SOD

(mg/kg)

 

V5

 

0-0.5

0.3-0.5

1.3-1.5

2.3-2.5

3.3-3.5

5.3-5.5

8.2-8.4

30.18

39.13

51.38

18.13

33.17

20.12

22.7

1.8

2.5

3.4

0.012

3.2

0.43

0.01

388

246

549

285

421

48

272

 

V6

 

0-0.5

0.4-0.6

1.4-1.6

2.4-2.6

3.45-3.65

5.7-5.9

65.41

37.96

42.83

36.4

33.04

20.62

 

3.6

1.9

2.2

1.9

1.4

0.01

1361

1509

907

2008

542

50

 

V7

 

0-0.5

1.15-1.35

2.15-2.35

3.15-3.35

6.25-6.45

9.25-9.45

11.7-11.9

44.89

46.83

29.36

30.79

40.06

16.67

14.36

2.6

2.5

0.55

0.45

2.60

0.01

0.01

409

3274

158

46

431

16

19

 

V8A

 

0-0.5

1.8-2.0

2.7-2.9

3.7-3.9

4.7-4.9

7.7-7.9

57.86

39.72

55.62

26.09

26.46

20.37

3.4

3.7

3.8

0.58

<0.01

0.06

1399

705

3037

142

88

154

 

V9B

 

 

0-0.5

1.7-1.9

2.7-2.9

3.7-3.9

6.8-7.0

7.8-8.0

62.95

68.99

43.5

40.99

20.98

17.51

3.2

16.0

2.8

0.88

0.78

0.13

1514

1735

191

333

279

90

 

Mean (all samples):

36.10

2.08

706.44

 

Mean (top 5m):

41.81

2.71

951.00

 


Background

6.2.3                 Typically, landfill gas hazard assessment has been undertaken using guidance or standards based on the concentrations of gases (methane and carbon dioxide), rather than mass flow rates.  Such guidance usually recommends restrictions on development in areas where the gas concentration exceeds a stated proportion of the lower explosive limit (LEL) of methane, which is 5% (v/v).  Typical margins of safety are in the range of 1-20% of LEL (0.05 - 1% (v/v)).

6.2.4                 Most of the guidance on this subject has been developed for application to sanitary landfill sites and much less has been written on the subject of standards or guidance for levels of methane arising from other sources, such as natural peat formations, marshland, rice paddies, coal measures and other organic deposits of anthropogenic origin, such as marine sediments.  In fact, methane arises naturally in many areas which have apparently been safely developed or redeveloped without any regard for gas protection measures.

Development of Guide Levels

6.2.5                 There is no primary legislation in Hong Kong covering hazards to development caused by landfill gas, or methane gas generated from anthropogenic organic deposits.  The most relevant guidance is the guideline, “Landfill Gas Hazard Guidance Note” issued by the Environmental Protection Department (EPD).  The guidance note states that no works and no entry to the development site should be allowed and the personnel on-site should be evacuated if the methane concentration of the development site exceeds 1.0% (v/v).

6.2.6                 Perhaps the best example of methane problems arising from anthropogenic organic deposits is that of the London Docklands.  During redevelopment of this area, where disused docks containing contaminated silts and sediments had been backfilled, methane concentrations of 20 - 30% were commonly found in monitoring boreholes[1], but in the majority of cases emission velocities from a 50 mm dia. borehole were below 0.01 ms-1.  Carpenter therefore recommended that development should not take place where emission rates exceed 0.05 ms-1 in a 50 mm diameter borehole.  This is the same as a flux of 0.05 m3m-2s-1 or 4320 m3m-2d-1 through a surface with a cross-sectional area equivalent to the cross-sectional area of the borehole (i.e. p r2, where r is the radius of the borehole).  Reference is also made to Carpenter’s work in the ICRCL guidance on the development and after-use of landfill sites[2].

6.2.7                 The UK Department of the Environment Waste Management Paper on Landfill Completion[3] recommends as a completion criterion that methane emission rates from monitoring boreholes should fall consistently below 0.015 m3h-1.  The completion criterion is that which must be met in order for monitoring to be discontinued and for the operator to surrender the licence which obliges him to maintain aftercare of the site.  It is generally taken as an indication that the site does not pose continuing threat to the environment.  For a borehole with a diameter of 100 mm (the minimum recommended in Waste Management Paper 26A) having a cross sectional area of 7,854 mm2 this is equivalent to 45.84 m3m-2d-1.  For  larger  boreholes  of  up  to  250 mm diameter, the equivalent rate would be 7.35 mm–2d-1.

6.2.8                 The above derived values are not the equivalent of gas fluxes through a freely-venting surface. For landfills in the UK in particular, the guidance assumes a capping layer of low permeability. In these cases a borehole installed through the cap acts to release static gas pressure in the fill. As a result, the flow of gas from the borehole will represent the flux through a freely-venting surface of greater cross-sectional area than the borehole itself because gas will be drawn from the surrounding area to the borehole under the influence of the pressure gradient.  It is difficult to estimate the radius of influence of such boreholes.  In sanitary landfills, radii of influence of 25m can be achieved under active pumping at pressures of 5 mbar.  Assuming a linear relationship and a static pressure of 0.5 mbar the radius of influence of the borehole would reduce to 2.5m.  If the emission from the borehole is assumed to be equivalent to the flux over an area of radius 2.5 m, the resultant flux would range from 18.3 l m-2d-1 (based on the recommendation of the Waste Management Paper No. 26A) to 432 l m-2d -1 (based on Carpenter’s guidance level).

6.2.9                 The UK Department of the Environment Waste Management Paper No. 26A on Landfill Completion also recommends a maximum acceptable rate of methane ingress into a building constructed on a disused landfill site.  This criterion was developed to determine when monitoring of landfill gas emissions at a restored landfill can be discontinued and when the site can be used for unrestricted development.  It is assumed that the most sensitive ‘at risk’ room or void has a height of 2.5m and a very low rate of ventilation of 1 air change per week.  For Yau Tong Bay Development, it is considered more appropriate to adopt a height of 1 m to represent the void space (to allow for smaller void spaces such as utilities or services ducts) and a ventilation rate of 1 air change per day (this is in line with rates of natural ventilation for closed rooms).  The maximum safe rate of methane ingress was then defined as that at which it would take 1 day for the methane concentration to reach 1% (v/v).  This is 20% of the lower explosive limit (LEC) for methane and provides a safety factor of 5.  The corresponding daily maximum “safe” rate of methane gas emission per unit area is calculated to be 10 L m-2 per day. [4] 

6.2.10              The EPD’s guidance note on landfill gas hazard and the UK guidance values (i.e. the UK completion criterion for landfills; the Carpenter’s guidance level and the “safe” gas emission rate), will be adopted as the assessment criteria (Table 6.2).


Table 6.2  Methane Hazard Assessment Criteria

 

EPD’s Guidance Note (% v/v)

UK Guidance Values  (l m-2 d-1)

11

182 – 432 3

104

Notes:

1.      Guideline value from Landfill Gas Hazard Guidance Note, EPD, HK.

2.      UK Landfill Completion Criterion from Department of Environment (1993) Landfill Completion. Waste Management Paper No. 26A, London: HMSO.

3.      Carpenter’s guidance levels.

4.      Maximum “safe” rate of gas emission derived for YTB from Department of the Environment (1993) Landfill Completion.  Waste Management Paper No. 26A.  London: HMSO.

 

6.3                      Calculation of Potential Gas Emissions

6.3.1                 From Table 6.1, the calculated mean TOC level is 2.71% on a dry weight basis and the calculated mean SOD level is 951 mg kg-1.  Based on an average moisture content of 41.8%, dry  matter made up 58.2% of the sediment on average.

6.3.2                 The potential methane gas emission was estimated based on the assumption that all marine mud would be left in-situ within the reclamation area for both the Full Reclamation and Minimized Reclamation, and that only the dredged mud from the seawall foundation would be disposed off-site.  The quantity of mud was estimated to be 900,000 m3  for the Full Reclamation:

 

Volume of mud left in-situ     =      Total area of reclamation (excluding the volume

                                                       of mud dredged from seawall foundation)

                                                       x depth of sediment    

                                               =      180,000 m2 x 5 m

                                               =      900,000 m3

 

6.3.3                 The quantity of mud was estimated to be 600,000 m3 for the Minimized Reclamation option.

6.3.4                 The capping of the reclamation would likely create underlying anaerobic conditions which favour degradation of organic matter by microbial activity in the contaminated sediment.  The end product of this degradation is biogas, which mainly consists of methane (CH4) and carbon dioxide (CO2).

6.3.5                 The rate of biogas generation is dependent on the amount of organic matter, degradability of organic matter, extent of anaerobic conditions, temperature, and transport medium for bacteria (water). Although the available information is limited, a theoretical calculation can be made for an estimate of biogas generation within the reclamation area.

6.3.6                 From experience in several anaerobic degradation projects (with waste as well as sludge), it is known that the biogas formation can be described as a first order degradation process. This process is characterized by high gas generation rates at the start, followed by an exponential decrease over the course of time.  Biogas generation can be calculated based on the available data on organic matter content or sediment oxygen demand (SOD).

6.3.7                 Not all organic carbon present in the sediment would be biodegradable.  The SOD represents the biodegradable fraction of the organic carbon present in the sediment and thus is convertible to methane.  Under anaerobic conditions, all of the oxygen demand of degradable organic material is preserved in the methane formed.  The following equation shows that 4 g of oxygen demand would have a total yield of 1 g of methane (the molar mass of methane is half the molar mass of oxygen and two moles of oxygen are required to oxidize one mole of methane).

 

CH4     +          2O2  =        CO2  +    2H2O

No. of moles    1                      2

 

6.3.8                 As an example, a sediment with a SOD of 200 mg m-3 will ultimately generate 50 mg of methane, equivalent to 0.07 litre of methane per m3 of sediment at standard temperature and pressure (STP).

6.3.9                 It is assumed that 50% of the gas produced from anaerobic degradation of organic matter of the sediment is methane (the remainder being carbon dioxide).  This is true for substrates such as carbohydrates that are neither highly oxidized nor highly reduced:

 

2CH2O       --->                  CH4     +          CO2

 

6.3.10              On that basis, the mass of methane generated from unit mass of TOC is calculated as follows:

 

2C             --->                  CH4     +          CO2

2 x 12 = 24                                    16

 

i.e. methane potential = 16/24 = 0.67 times TOC

 

6.3.11              Assuming a SOD in the material to be contained in the future reclaimed land of  951 mg kg-1, the total methane potential would be 237.8 mg kg-1, or assuming a dry matter content of 58.2%,  408.6 mg kg-1.  However, SOD represents only a fraction of the organic carbon present in the sediment.  Based on a sediment TOC of 2.71% of dry matter and assuming that half is converted to methane (the remainder being carbon dioxide), methane potential would be about 18,172.4 mg kg-1 dry matter.  This implies that only 2.25% of TOC represents readily biodegradable organic matter.  Use of TOC to estimate methane potential therefore provides an over-estimate of that potential.  Furthermore, some organic substrates which are degradable aerobically (and which therefore contribute to SOD) are not degradable at all in anaerobic conditions.  Therefore, basing potential methane yield on SOD itself probably provides an over-estimate of methane potential. 

6.3.12              It is difficult to estimate the half life of substrates in systems such as contaminated marine sediment.  However, at low substrate concentrations in engineered systems such as facultative ponds, half lives of substrates in the anaerobic could be of the order of half a year.  In landfills, the average half life of organic substrates could be 5 years.  Hence, for conservatism, the methane potential is calculated based on TOC, rather than SOD because the former represents the extreme worst case assuming all organic matter is biodegradable and convertible to methane.  In fact, as indicated above, probably only 2.25% of the organic carbon is readily degradable.  Thus, an analysis based on TOC alone will overestimate the impact by a factor of about forty.

6.3.13              Based on the range of half-lives of 0.5-5 years, the peak annual methane potential would be between 13 and 75% of the total, i.e. 2,362 – 13,629 mg kg-1.  The peak annual methane potential corresponding to a half life of decay of 0.5 years, is actually not significant in terms of development because after two years over 90% will have degraded and the flux will have fallen proportionately to a rate less than that of the lower figure after the same time.  Therefore, the peak annual methane potential based on a half-life of 5 years is adopted for the calculations of potential methane gas emission for the comparison with the UK methane hazard assessment criteria.  A half-life of 2 years is also adopted for the calculation of potential methane gas emission to represent a worst-case scenario (as a half-life of 2 years will result in a higher flux rate at 2 years after reclamation than that resulting from a half-life of 5 years).  Table 6.3 shows calculations of the peak annual methane potential and the daily potential methane flux from the Yau Tong Bay Reclamation for the Full Reclamation option as this represents the worst case scenario with a greater volume of marine mud left in-situ.  Although it should be noted that the potential methane flux would be the same for the Full Reclamation or Minimum Reclamation Options as the flux represents an area emission rate (i.e. rate at which gas is emitted per unit area of the reclamation).

6.3.14              The methane concentrations of the boundary layer at the surface of the Yau Tong Bay Reclamation is also estimated as shown in Table 6.3 for the comparison with the guideline value (1% v/v) as stipulated in EPD’s Landfill Gas Hazard Guidance Note.  The boundary layer is assumed to be 1 m to represent a conservative scenario.

 

Table 6.3  Calculation of Methane Flux from the Yau Tong Bay Reclamation

 

 

Marine Sediment

Full Reclamation Option

Methane Hazard Assessment Criteria

Half-life cycle of 5 years

Half-life cycle of 2 years

Volume (m3)

900,000

(600,000)e

900,000

(600,000)e

 

Density (kg m-3)

1,750

1,750

 

Dry matter (% w/w)

58.19

58.19

 

Dry matter (kg m-3)

1018.33

1018.33

 

TOC (%)

2.71

2.71

 

TOC (kg m-3)

27.60

27.60

 

CH4 potential (kg m-3)

18.49

18.49

 

Peak annual CH4 potential (kg)

2,163,298 (1,442,199) e

4,825,819 (3,217,213) e

 

Total area (m2)

180,000

(120,000) e

180,000

(120,000) e

 

Total potential CH4 flux (kg m-2 yr-1)

12.02

26.81

 

Total potential CH4 flux (g m-2 yr-1)

12018.32

26810.10

 

Total potential CH4 flux (mol m-2 yr-1)

751.15

1675.63

 

Total potential CH4 flux (l m-2 yr-1)

16825.65

37534.15

 

Total potential CH4 flux (l m-2 dy-1) (assuming 2.25% of TOC biodegradable)

1.04

2.31

18a – 432b

10d

Total potential CH4 flux (l m-2 dy-1) (assuming 15% of TOC biodegradable)

6.91

15.42

Total potential CH4 flux (l m-2 dy-1) (assuming 50% of TOC biodegradable)

23.05

51.42

Total potential CH4 flux (l m-2 dy-1) (assuming 100% of TOC biodegradable)

46.10

102.83

Potential CH4 concentration (% v/v) at the surface boundary layer (assuming 2.25% of TOC biodegradable)

0.10

0.23

1c

 

Potential CH4 concentration (% v/v) at the surface boundary layer (assuming 100% of TOC biodegradable)

4.61

10.28

Notes

a      UK Landfill Completion Criterion from Department of the Environment (1993) Landfill Completion.  Waste Management Paper No. 26A.  London: HMSO.

b      Carpenter’s guidance level from Carpenter, R J (1988) Building development on disused landfill sites - overcoming the landfill gas problem.  In: Proc. 5th International Solid Wastes Conference, Copenhagen, Denmark, Vol., pp 153-160. London: Academic Press.

c      Guideline value from Landfill Gas Hazard Guidance Note, EPD, HK.

d      Maximum “safe” rate of gas emission derived for YTB, as based onDepartment of the Environment (1993) Landfill Completion.  Waste Management Paper No. 26A.  London: HMSO.

e      Values in brackets are for the Minimum Reclamation Option.  The total potential methane flux is the same for the Full Reclamation or Minimum Reclamation Options as the flux represents an area emission rate (i.e. rate at which gas is emitted per unit area of the reclamation). 

6.3.15           The above analysis is based on a number of broad assumptions which might affect the precision of the estimates.  Furthermore, it takes no account of biological methane oxidation that will probably occur in the upper layers of the sediment.  In the case of a uniform emission through a permeable, aerobic reclamation layer, methane (or part of it) can be oxidised microbiologically.  In the literature, oxidation efficiencies can be found of 2% up to 100%[5].  For landfills, covered by a very permeable top layer, oxidation efficiencies were found in the range of 0-50% [6].  High efficiencies will only occur when the fill material is well aerated (e.g. by diffusion of air) and the gas is able to emit uniformly over the surface area.  Low efficiencies, however, will occur when the fill material is poorly permeable for gases and when the gas generation rate is rather high, so that concentrated emissions can take place via fissures, or other preferential pathways (e.g. gravel layers).

6.4                       Evaluation of Significance of Potential Gas Emissions

Significance of potential methane emissions with reference to the UK Guidance Values

6.4.1                 Taking the UK landfill completion criterion (i.e. 18 l m-2d-1) as the standard, the predicted methane emission from the Full or Minimized Reclamation options based on a half-life of 5 years (1.04 l m-2d-1), assuming 2.25% of TOC biodegradable, is only 5.7% of this guide value.  This is therefore insignificant, since provides a safety factor of approximately 17.  Based on a half-life of 2 years, the predicted methane emission (2.31 l m-2 per day) is 12.8% of the UK landfill completion criterion, providing a safety factor of approximately 8.  The predicted methane emission based on the assumption of 100% TOC biodegradable, though which is highly unlikely, is also considered as a conservative estimate.  The methane emission (46.10 l m-2 d-1) for a half-life of 5 years is found to be approximately 2.5 times greater than the UK landfill completion criterion.  Under the worst case scenario of a half-life of 2 years, the predicted methane emission (102.83 l m-2 per day) is found to be approximately 5.7 times greater than the UK landfill completion criterion.

6.4.2                 The calculations show that the predicted methane emission based on a half-life of 5 years, assuming 100% of TOC biodegradable, is about 10.7% of the Carpenter’s guidance level (i.e. 432 l m-2 d-1), providing a safety factor of approximately 9.  The predicted methane emission based on a half-life of 2 years, assuming 100% of TOC biodegradable, is about 23.8% of the Carpenter’s guidance level, providing a safety factor of approximately 4.  It is noted that even under the extreme worst case scenario with the predicted methane emission in exceedance of the UK landfill completion criterion, the methane emission is well below the upper UK guide value, which is the level at which development would be restricted according to Carpenter’s guidelines.

6.4.3                 Taking the “safe” rate of gas emissions derived for YTB from Waste Management Paper No. 26A on Landfill Completion (i.e. 10 l m-2d-1) as the standard, the predicted methane emission from the Full or Minimized Reclamation options, assuming 2.25% of TOC biodegradable, is about 9 times less than this guide value.  The predicted methane emission based on the worst case assumption of 100% TOC biodegradable, which is considered a highly unlikely event, is also considered as a conservative estimate.  The calculations show that the predicted methane emission (46.10 l m-2 d-1), assuming 100% of TOC biodegradable, is approximately 4.6 times greater than the “safe” emission rate  (i.e. 10 l m-2 d-1).  Taking the worst case scenario of a half-life of 2 years, the calculations show that the predicted methane emissions are approximately 4 times less and 10 times greater than the “safe” emission rate, assuming 2.25% and 100% of TOC biodegradable, respectively.  

6.4.4                 The derived maximum “safe” rate of gas emissions is based on a number of assumptions regarding the size and rate of ventilation of the ‘at risk’ room, and the permeability of the ground surface at the site.  It is therefore necessary to consider the most sensitive ‘at risk’ features of the proposed development at Yau Tong Bay in order to determine the likelihood of methane emissions posing a significant risk and the need for mitigation measures.

6.4.5                 The proposed reclamation will be developed for residential/commercial uses and open space.  The proposed high rise residential buildings with a podium design tend to pose limited risk as these do not have any below ground rooms and car parking is on lower storeys of the building.  Similarly, the commercial towers and shopping arcade comprising above ground structures pose limited risk.  Rooms located at the ground level of the commercial and residential buildings, such as utility (services) and refuse collection rooms, may be susceptible to ingress of any biogas generated from the reclamation if mitigation measures are not included in the design of the building.  Rooms on the ground floor of schools may also be ‘at risk.’ The most sensitive ‘at risk’ rooms are considered to be the underground car parks which would be susceptible to ingress and accumulation of any biogas emissions from the reclamation.  It will therefore be necessary to ensure adequate ventilation of the underground car parks to prevent the accumulation of any methane gas emissions to dangerous concentrations.  This precautionary measure and other recommended gas protection measures for both the ground level and underground structures at the development are discussed in Section 6.5.  

6.4.6                 The development will include some cover in the form of non-permeable concrete or asphalt layers.  These layers decrease the possibilities for bacteriological oxidation of methane in the top layer.  This might result in more concentrated emissions or accumulation of methane in cavities.  Therefore, if the precautionary principle is to be applied, it is recommended to incorporate gas protection measures and to undertake methane gas monitoring in the immediate post-reclamation period to measure methane concentrations in the fill.

Significance of potential methane emissions with reference to EPD’s Landfill Gas Hazard Guidance Note

6.4.7                 The methane concentration at the surface boundary layer from the Full or Minimized Reclamation options is estimated to be 0.10% (v/v) (assuming 2.25% of TOC biodegradable and a half-life of 5 years) which is 10 times less than the guide value of 1% (v/v), as stipulated in EPD’s Landfill Gas Hazard Guidance Note.  Based on the worst case scenario of a half-life of 2 years, the estimated methane concentration of 0.23% (v/v) is 4 times less than the EPD’s guide value.

6.4.8                 On considering the highly unlikely event of assuming 100% TOC biodegradable, the methane concentration at the surface boundary layer from the Full or Minimized Reclamation options is estimated to be 4.61% and 10.28% based on a half-life of 5 and 2 years, respectively, which is in exceedance of the EPD’s guide value.  It is therefore recommended that the above precautionary approach be adopted.  Mitigation requirements are discussed in Section 6.5 below.

6.5                      Mitigation Measures And Further Work

6.5.1                 The methane calculations provided above are based on numerous theoretical assumptions and there is virtually no precedent established on practical grounds against which they can be tested.  It is therefore recommended to establish gas monitoring boreholes immediately after reclamation and prior to development to determine actual rates of methane gas emissions generated from the marine sediment underlying the reclamation. The predicted methane emissions based on the conservative assumption of 100% biodegradable TOC are well below the upper UK guide value (which is the level at which development would be restricted according to Carpenter’s guidelines). The recommended monitoring requirements are detailed below and apply to both the Full and Minimized Reclamation options. 

6.5.2                 The potential biogas risk has been assessed based on the predicted peak methane generation potential and total daily methane flux (based on the TOC results and assuming all organic matter is biodegradable).  Based on this conservative approach, the predicted daily methane flux is higher than the UK “safe” rate of methane gas emission (as derived from Waste Management Paper No. 26A for methane ingress into an ‘at risk’ room within a building constructed on a restored landfill site).  As discussed in paragraph 6.4.4, the UK maximum “safe” rate of landfill gas emissions is based on a number of assumptions regarding the size and rate of ventilation of the ‘at risk’ room or void space.  This criterion was developed to determine when monitoring of landfill gas emissions at a restored landfill can be discontinued and when the site can be used for unrestricted development.

6.5.3                 As sensitive ‘at risk’ rooms have been identified at the proposed development, both at ground level and below ground, it is recommended that a precautionary principle be applied.  Gas protection measures are therefore recommended to be incorporated in the building design.  Given that mitigation measures to prevent the ingress and / or accumulation of any methane gas emissions generated from the reclamation may be very costly, it is proposed that the results of the recommended gas monitoring to be undertaken at the YTB reclamation be reviewed against a trigger value and thereby determine the extent and type of mitigation measure requirements to be incorporated in the detailed design of the proposed development. 

Gas Monitoring

6.5.4                 Monitoring should be undertaken via purposely installed monitoring wells within boreholes drilled into the fill material.  The boreholes should be drilled down to the level of the groundwater (mean sea water level) and standard landfill gas-type monitoring wells installed.  During the drilling of boreholes, the safety and working procedures described in the EPD Landfill Gas Hazard Assessment Guidance Note (1997) should be followed.  It is recommended that the monitoring wells be installed in an approximately even distribution across the reclamation area.  Proposed monitoring locations are indicated in the EM&A Manual. 

6.5.5                 Concentrations of methane gas should be measured using intrinsically safe, portable gas monitoring instruments.  Fluxes should also be measured if the emission velocities are not too low.  It is recommended that monitoring be undertaken monthly for a period of at least one year prior to the commencement of construction works on the reclamation.  The results of the gas monitoring should be reviewed to determine whether the length of the monitoring period should be extended beyond one year.  Details of the recommendations for methane gas monitoring are given in the EM&A Manual.

Precautionary Gas Protection Measures

General Guidelines

6.5.6                 At this stage it is difficult to formulate specific guidelines on what measures would be required for the measured rates of gas emission as this would depend on the detailed design of the individual buildings to be constructed.  The following criteria may be used as general guidelines.  The maximum “safe” rate of methane gas emission of 10 L m-2 per day derived from the Waste Management Paper No. 26A on Landfill Completion is proposed to be adopted as the trigger value.

Scenario 1

6.5.7                 If rates of methane emission are consistently much less than the trigger value (10 L m-2 per day), including monitoring occasions when atmospheric pressure is falling rapidly, then it is considered that the buildings will not require gas protection measures.

6.5.8                 The trigger value is an area emission rate (that is, rate at which gas is emitted per unit area of the reclamation).  In order to convert this into an emission rate from a borehole, it is necessary to make an assumption about the "area of influence" of a freely venting borehole which depends on a number of factors.  A key factor is the ease by which gas can escape from the surface of the site.  For a site with cover in the form of low permeability paving or concrete, it would be expected that a borehole would have a much greater area of influence than if the site had soft landscaping.

6.5.9                 To be conservative, it is proposed to adopt an area of influence of 20 m2 (radius of 2.5m)[7], which would give:

·       Trigger value of 10 L m-2 per day x 20 m2  =  200 L per day emitted from the borehole

6.5.10              The criterion for “safe” flow rate from a free venting borehole becomes:

·       Flow rate of methane (in terms of litre per day) < 200 L per day  or

·       (Gas flow rate in terms of litre per day) x (concentration of methane in gas (in % gas)) < 200 L per day

Scenario 2

6.5.11              If the rate of methane emission frequently exceeds the trigger value or shows a rising trend such that future emission rates are likely to exceed the trigger value, then any buildings to be constructed on that part of the site will require some form of gas protection measures, that is,

·       (Gas flow rate in terms of litre per day) x (concentration of methane in gas (in % gas)) >  200 L per day.

6.5.12              The type of gas protection measures would be dependent on the design and use of the particular building.  Possible measures are the incorporation of a low gas permeability membrane in the floor slab of the building or mechanical ventilation of ‘at risk’ rooms.  Further investigation may be required to determine the area of land which is affected by gas emissions.  The analysis and assessment of the results and design of any gas protection measures should be undertaken by suitably qualified and experienced professionals who are familiar with the properties of biogas and building protection design measures.

Scenario 3

6.5.13              If there are occasional exceedances of the trigger value for methane emission rate from a borehole or if there is a significant fluctuation of the monitoring results with some readings coming close to the trigger value, then any trends in the results will need to be assessed to determine their significance and the need for any building protection measures.  It may be necessary to undertake further monitoring by extending the monitoring period, for example, if a spuriously high reading is noted towards the end of the monitoring period or if it seems likely that future emission rates may exceed the trigger value.  The analysis and assessment of the monitoring results and design of any gas protection measures should be undertaken by suitably qualified and experienced professionals who are familiar with the properties of biogas and building protection design measures.

Scenario 4

6.5.14              If the rate of methane emission from any borehole frequently exceeds the upper UK guidance value of 432 L m-2 per day (that is, Carpenter’s guidance level at which it is recommended that development should not take place), or shows a rising trend such that future emission rates are likely to exceed this value, then no buildings should be constructed on that part of the site.  That is when:

·       Upper UK guidance value of 432 L m-2 per day x 20 m2  =  8,640 L per day  emitted from the borehole; or

·       (Gas flow rate in terms of litre per day) x (concentration of methane in gas (in % gas)) > 8,640 L per day.

6.5.15              Depending on the monitoring results, it may be necessary to incorporate a number of gas protection measures into the design of the proposed development.  Specific details cannot be provided until the results of the monitoring are available, and the building detailed designs are known and confirmed.  A combination of different measures may be used for protecting both the ground level and underground structures at the development against possible risks due to biogas emissions.  Discussions would need to be held with the developer and architects to determine the protection measures which are the most appropriate and feasible.   At this stage, discussions with the architect have identified feasible gas protection measures that may be adopted to prevent the ingress and/or accumulation of any methane gas emissions generated from the reclamation.  These gas protection measures are described below and would apply to both the Full and Minimized Reclamation options. 

Protection of Above Ground Structures

6.5.16              Passive sub-floor ventilation may be incorporated in the building design for those buildings with no underground basement or rooms. The general principle of passive sub-floor venting is shown in Figure 6.1.  Passive control measures for buildings to prevent gas build-up involve the creation of a clear void beneath the structure allowing natural air movements such that any emissions of gas from the ground are mixed and diluted by air.

Measures to Prevent Ingress of Gas into ‘At Risk’ Rooms

6.5.17              To prevent the ingress of methane gas into a building, a low gas permeability membrane may be incorporated in the design of the floor and any below ground walls of identified ‘at risk’ rooms (e.g. rooms housing electrical equipment, pumps or switchgear).  In addition, measures should be taken to avoid or seal any openings in the floor (e.g. at services entry points).  Such techniques are commonly used where there is a risk of landfill gas entering a building and have been employed on a number of developments in Hong Kong.

6.5.18              There are various proprietary products available in the market and the specific details of their application will depend on the detailed design of the ‘at risk’ rooms.  Possible measures include gas-resistant polymeric membranes which can be incorporated into the floor or wall construction as a continuous sealed layer.  Membranes should be able to demonstrate low gas permeability and resistance to possible chemical attack.  Other building materials such as dense well-compacted concrete or steel shuttering also enhance resistance to gas permeation.  In all cases, extreme care is needed during the installation of the membrane and subsequent construction works to avoid damage to the membrane.  Typical design details for gas impermeable membrane protection are shown on Figure 6.2.

Ventilation within ‘At Risk’ Rooms

6.5.19              As an additional measure for the protection of specific ‘at risk’ rooms, mechanical ventilation may be provided to ensure that if any gas enters the room it is dispersed and cannot accumulate to potentially dangerous concentrations.  For particularly sensitive rooms, such as below ground confined spaces which contain sources of ignition, forced ventilation may be used in addition to the use of a low gas permeability membrane. 

6.5.1                 Three basement carparks are proposed at the Yau Tong Bay development which would be susceptible to ingress and accumulation of any biogas emissions from the reclamation.  The storey height of each basement carpark is 4 m, with 2.4 m clear headroom (minimum) at driveway and carpark.  With reference to the Waste Management Paper No. 26A (para. 6.2.9), the maximum safe rate of methane ingress is defined as that at which it would take 1 week for the methane concentration to reach 1% (v/v).  The corresponding daily maximum “safe” rate of methane gas emission per unit area for the basement carpark is calculated to be 3.43 1 m-2d-1 (assuming a height of 2.4 m and no ventilation).  This emission rate is expressed as a daily rate and is based on an assumed accumulation of gas at this daily emission rate over a period of one week.

6.5.2                 The predicted peak daily methane flux (based on the TOC results, a half-life of 2 years and assuming all organic matter is biodegradable) is 102.83 1 m-2d-1.  Based on this conservative approach, the predicted daily methane flux is 30 times greater than the calculated maximum “safe” rate of methane gas emission for the basement carpark.  To achieve this recommended daily “safe” rate, a minimum of 30 air changes per week would be required.  The basement carpark ventilation systems will be designed to ensure that the car park air quality guidelines given in ProPECC PN 2/96 Control of Air Pollution in Car Parks are achieved. The normal ventilation rate for the basement carpark is 5 to 6 air changes per hour in order to comply with the EPD requirement on carbon monoxide concentrations within carparks. Therefore, the ventilation rate proposed at the basement carpark (around 120 air changes per day) to satisfy the air quality guidelines is well above that required to achieve the daily “safe” rate of methane gas emission per unit area.

6.5.3                 Several ventilation systems would be installed and evenly distributed within the basement carpark.  Therefore, even during equipment failure, it is unlikely that the entire exhaust system would break down.  To cater for the situation of power failure, it is recommended that a back-up power supply be provided for the ventilation system so that certain designated exhaust systems would still operate.  Under normal conditions, the power failure should be rectified within several hours.

Protection of Utilities or Below Ground Services

6.5.4                 Below ground ducts or trenches for the installation of utilities or services (e.g. telecommunications, gas, water, electricity supply or drainage connections) would be particularly prone to the ingress and accumulation of any biogas emissions.  It is therefore important to prevent such ducts and trenches acting as routes by which gas may enter buildings by avoiding, as far as possible, the penetration of floor slabs by such services.  In addition, any unavoidable penetrations should be carefully sealed using puddle flanges, low permeability sealant and/or membrane.

Precautions During Construction Works

6.5.5                 Special care must be taken during the first two years of construction activities on the reclamation. Sub-surface excavations into the mud layers might encounter gas occasionally, but not at levels likely to be dangerous provided that the gas vents freely to atmosphere.  Emission rates are unlikely to be sufficient to sustain a flame.  These gas bubbles will only occur for short periods, and therefore, as a precaution, smoking and naked flames in the vicinity of drilling activities and excavations of 1m depth or more should be prohibited.

6.5.6                 Precautions may be required to ensure that there is no risk due to the accumulation of gas within any temporary structures, such as site offices, during construction works on the reclamation area.  It may be necessary, for example, to raise such structures slightly off the ground so that any gas emitted from the ground beneath the structure may disperse to atmosphere rather than entering the structure.  A minimum clear separation distance of 500mm, as measured from the highest point on the ground surface to the underside of the lowest floor joist, is recommended in the Landfill Gas Hazard Assessment Guidance Note, EPD (1997).

Precautions Prior to Entry of Below Ground Services

6.5.7                 Following construction, accumulation of gas within any below ground services can pose a risk to the staff of the utility companies.  As a good working practice, prior to entry into any confined space within the reclamation site (such as manholes, underground culverts and utility casings), the gas atmosphere within the confined space should be monitored for oxygen, methane and carbon dioxide.  Personnel should be made aware of the potential dangers and advised to take appropriate precautions.

6.5.8                 The working practices should follow the Landfill Gas Hazard Assessment Guidance Note, EPD (1997) guidelines as follows:

·       Any chamber, manhole or culvert which is large enough to permit access to personnel should be subject to entry safety procedures. Such work in confined spaces is controlled by the Factories and Industrial Undertakings (Confined Spaces) Regulations of the Factories and Industrial Undertakings Ordinance. Following the Safety Guide to Working in Confined Spaces ensures compliance with the above regulations.

·       The entry or access point should be clearly marked with a warning notice (in English and Chinese) which states that there is the possibility of flammable and asphyxiating gases accumulated within.

·       The warning notice should also give the telephone number of an appropriate competent person who can advise on the safety precautions to be followed before entry and during occupation of the manhole.

·       Personnel should be made aware of the dangers of entering confined spaces potentially containing hazardous gases and, where appropriate, should be trained in the use of gas detection equipment.

·       Prior to entry, the atmosphere within the chamber should be checked for oxygen, methane and carbon dioxide concentrations. The chamber may then only be entered if oxygen is greater than 18% by volume, methane is less than 10% of the Lower Explosive Limit (LEL), which is equivalent to 0.5% by volume (approximately), and carbon dioxide is less than 0.5% by volume.

·       If either carbon dioxide or methane are higher, or oxygen lower, than the values given above, then entry to the chamber should be prohibited and expert advice sought.

·       Even if conditions are safe for entry, no worker should be permitted to enter the chamber without having another worker present at the surface. The worker who enters the chamber should wear an appropriate safety/recovery harness and, preferably, should carry a portable methane, carbon dioxide and oxygen meter.

6.5.9                 In general, when work is being undertaken in confined spaces sufficient approved resuscitation equipment, breathing apparatus and safety torches should be available. Persons involved in or supervising such work should be trained and practised in the use of such equipment. A permit-to-work system for entry into confined spaces should be developed by an appropriately qualified person and consistently employed.

6.6                       Conclusions

6.6.1                 Organically enriched material is planned to be left in-situ beneath the YTB Full Reclamation or Minimized Reclamation Options.  As methane gas could be generated under anaerobic conditions, there is a potential for this gas to be released either during construction or after development of the reclaimed area.

6.6.2                 The calculation of the total potential methane flux was overly conservative in nature in order to build-in a large margin of safety. Conservative assumptions included the following:

·       All the TOC is readily biodegradable.

·       All the organic matter is degraded to methane and no re-oxidation in surface layers occurs. (In fact, oxidation may occur in the upper layers of fill.  Methane passing up through such layers may be partially or even totally destroyed by oxidation).

·       Higher methane fluxes can be ignored as they are based on a half-life of only 0.5 year, which would result in 90% of the methane being lost to atmosphere prior to the YTB development.

·       A boundary layer of 1 m at the surface of the reclamation is assumed as a worst case scenario.

6.6.3                 Assuming 100% of TOC is biodegradable, a highly unlikely event, the predicted methane emission from the YTB Reclamation (Full Reclamation or Minimized Reclamation options) for a half-life of 5 years was found to be approximately 2.5 times greater than the UK landfill completion criterion.  Based on a half-life of 2 years, the predicted methane emission was found to be approximately 5.7 times greater than the UK landfill completion criterion.  Under this extreme worst case scenario, the predicted methane emissions based on half-lives of 5 and 2 years are well below the upper UK guide value, which is the level at which development would be restricted according to Carpenter’s guidelines.  This suggests that the methane gas generation potential is not expected to pose a development constraint to the YTB Full Reclamation or Minimized Reclamation options. These UK guidelines are considered to be consistent with current Hong Kong guidance. 

6.6.4                 In view of the exceedance of the UK landfill completion criterion and the identification of ‘at risk’ rooms at the development, it is recommended to undertake gas monitoring in the immediate post-reclamation period and prior to the commencement of construction works on the reclamation to measure methane concentrations in the fill and to determine actual rates of methane gas emissions.  The review of the monitoring results would determine the extent and type of gas protection measures to be incorporated in the building design to prevent the ingress and/or accumulation of any methane gas emissions to potentially dangerous concentrations.  Guidelines on criteria for evaluation of the gas monitoring results and gas protection measure requirements have been identified for both the ground level and underground structures at the development. 


6.6.5                 Precautionary measures to be taken prior to entry into any below ground services or confined space within the reclamation site are also recommended.  As a further precaution, naked flames should not be permitted during construction involving drilling or excavation.

6.6.6                 The proposed monitoring guidelines and other precautionary mitigation measures should be examined further at the detailed design stage with regard to the specific design details of individual buildings.  With the incorporation of the recommended gas protection measures in the design of the buildings, as necessary depending on the results of the monitoring, together with the implementation of the other recommended precautionary measures, the risk to people and property due to biogas emissions from the YTB Full Reclamation or Minimized Reclamation options is considered to be low.

 



[1]    Carpenter, R J (1988) Building development on disused landfill sites - overcoming the landfill gas problem.  In: Proc. 5th International Solid Wastes Conference, Copenhagen, Denmark, Vol., pp 153-160. London: Academic Press.

[2]    Interdepartmental Committee on the Redevelopment of Contaminated Land (1990) Notes on the Development and After-Use of Landfill Sites.  Guidance Note 17/78.  London: Department of the Environment.

[3]     Department of the Environment (1993) Landfill Completion.  Waste Management Paper No. 26A.  London: HMSO.

[4]      Agreement No. CE 70/97.  Green Island Development Engineering Investigation and Planning Review.  Environmental Impact Assessment Review - Biogas Assessment, March 2000, prepared by ERM Hong Kong Ltd.

[5] Hoeks, J., (1972). Effect of leaking natural gas on soil and vegetation in urban areas, Wagenin­gen

[6] (i) Orlich, J., (1990). Methane emissions from landfill sites and water waste lagoons, Federal Environ­ment Agency, Berlin

(ii) UK Department of the Environment, (1993). An assessment of methane emissions from UK landfills

(iii) US-EPA, (1993). Anthropogenic methane emissions in the United States: estima­tes for 1990

[7]      ERM Hong Kong Ltd. (March 2000).  Agreement No. CE 70/97, Green Island Development Engineering Investigation and Planning Review.  Environmental Impact Assessment Review - Biogas Assessment (Final).