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研究報告

CHAPTER 5 DATA UNCERTAINTIES

5.1 VOCS
   
The method detection limit of 0.2 ppbv for each target VOC was achieved. One collocated sample was collected every three months for evaluation of method precision, including both sampling and analysis performance. Tables 5.1a and 5.1b illustrates that the percentage difference between field samples and collocated samples were all below 20% for all target compounds, with the exception of trichloroethylene on 22nd April, 1999 (20.89) and 1,3-butadiene on 19th October, 1999 (20.29). But they remain acceptable under the precision test. The average percentage difference of methyl chloride, 1,3-butadiene, benzene, trichloroethylene and tetrachoroethene were 11.84%, 18.36%, 7.54%, 20.89% and 8.40% respectively.

Table 5.1a Percentage Difference Between VOC Field Samples and Collocated Samples
22-Apr-99 Field Sample
(ug/m3)
Collocated Sample
(ug/m3)
Percentage Difference
(%)
Methyl chloride 1.06 1.23 14.26
1,3-Butadiene 0.53 0.63 15.78
Benzene 5.96 6.85 12.90
Trichloroe thylene 1.99 2.51 20.89
Te trachloroe thylene 1.86 2.05 8.99

21-Jun-99

Field Sample
(ug/m3)
Collocated Sample
(ug/m3)
Percentage Difference
(%)
Methyl chloride

2.06

2.21

6.88

1,3-Butadiene 1.51 1.86 19.02
Benzene 6.42 6.98 8.04
Trichloroe thylene 0.55 0.55 --
Te trachloroe thylene 2.00 2.31 13.38

19-Oct-99

Field Sample
(ug/m3)
Collocated Sample
(ug/m3)
Percentage Difference
(%)
Methyl chloride 2.60 2.98 12.75
1,3-Butadiene 0.55 0.69 20.29
Benzene 3.87 4.02 3.69
Trichloroe thylene 0.55 0.55 --
Te trachloroe thylene 2.55 2.48 2.82

23-Jan-00

Field Sample
(ug/m3)
Collocated Sample
(ug/m3)
Percentage Difference
(%)
Methyl chloride 1.60 1.41 13.48
1,3-Butadiene 0.24 0.24 --
Benzene 3.71 3.51 5.56
Trichloroe thylene 0.55 0.55 --
Te trachloroe thylene 0.69 0.69 --

Table 5.1b Summary of Percentage Difference Between
VOCs Field Samples and Collocated Samples
Compounds Average Percentage Difference (%)
Methyl chloride 11.84
1,3-Butadiene 18.36
Benzene 7.54
Trichloroe thylene 20.89
Te trachloroe thylene 8.40

   
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最近修訂日期: 二零零五年十二月二十二日