|
An
examination of the organic contaminant concentrations
revealed that the majority of the samples were reported
below the analytical detection limits. Information presented
in Tables 3.4a and Table 3.4b indicates that only one
of the Polycyclic Aromatic Hydrocarbon (PAH) compounds
analysed, Naphthalene, was recorded at detectable levels
for at least 15% of the biota samples analysed in samples
collected during both the dry season (ie December 1998
and January 1999) and wet season (ie August 1999 and
September 1999). More individual PAHs were detected
in biota during the wet season sampling (August and
September 1999) though only Naphthalene was detected
frequently above the detection limit in tissue samples
(27% and 33% in August and September 1999, respectively).
Of the non-PAH organics, only Total DDT (Tables 3.4a
and 3.4b, Figure 3.4a and
3.4b) and Total PCBs (Figure
3.4c and 3.4d) were detected sufficiently frequently
above the detection limit to warrant further discussion.
TBT was only rarely detected in tissue samples above
the detection limit during both the dry (12% and 3%
during December 1998 and January 1999, respectively)
and wet season (3% and 0% during August and September
1999, respectively). Total PCBs occurred in less than
50% of biota samples during the dry season sampling
(ie December 1998 and January 1999) but conversely in
greater than 50% of samples during the wet season. Results
are also presented graphically for Naphthalene which
was the most frequently recorded PAH in the tissues
(Figure 3.4 e and 3.4f).
The
percentage of stations above the dl was chosen for statistical
reasons and follows procedures outlined in other international
marine environmental monitoring programmes. A discussion
of these statistical methods is provided in international
guidelines presented in Clarke & Brandon (1994)(19)
. The detection limits used in this Study were very
low and below applicable safety criteria. For example,
the detection limit for DDT was 0.15 ug kg-1 wet weight
and the USFDA action level guideline is 5 mg kg-1 wet
weight. The detection limits, therefore, represent very
low levels and values reported at or below can be placed
in context.
Table
3.4a Samples Collected from Monitoring Stations
During December 1998 and January 1999 Trawl Surveys
Which Exceeded the Detection Limit (dl) a |
Contaminants |
December
1998 Trawl Sampling |
January
1999 Trawling Sampling |
(in
Biota) |
No.
(%) of stations above dI |
Futher
analysis |
No.
(%) of stations above dI |
Futher
analysis |
Total
DDT |
54
(90%) |
Graphical
presentation with discussion and statistical analysis |
27
(73%) |
Graphical presentation with discussion and statistical
analysis
|
Total
PCBs |
27
(45%) |
Graphical
presentation only |
11
(30%) |
Graphical
presentation only |
TBT |
7
(12%) |
None |
1
(3%) |
None |
Acenaphthene |
0
(0%) |
None |
0
(0%) |
None |
Acenaphthylene |
0
(0%) |
None |
0
(0%) |
None |
Anthracene |
0
(0%) |
None |
0
(0%) |
None |
Fluorene |
0
(0%) |
None |
1
(3%) |
None |
Naphthalene |
7
(12%) |
Graphical
presentation with discussion |
10
(27%) |
Graphical
presentation with discussion |
Phenanthrene |
0
(0%) |
None |
0
(0%) |
None |
Low
Molecular Weight PAHs |
0 (0%) |
None |
0 (0%) |
None |
Benzo(a)anthracene |
0
(0%) |
None |
0
(0%) |
None |
Benzo(a)pyrene |
0 (0%) |
None |
0 (0%) |
None |
Chrysene |
0
(0%) |
None |
0
(0%) |
None |
Dibenzo(a,h)
- anthracene |
0 (0%) |
None |
0 (0%) |
None |
Fluoranthene |
0
(0%) |
None |
0
(0%) |
None |
Pyrene |
0 (0%) |
None |
0 (0%) |
None |
High
Molecular Weight PAHs |
0
(0%) |
None |
0
(0%) |
None |
Total
PAHs |
0 (0%) |
None |
0 (0%) |
None |
a
- 0% to 15% no presentation, 15% to 50% graphical presentation
(with discussion for naphthalene only), > 50% discussion
with graphical presentation and statistical analysis
if detected in greater than 60% of stations.
Table
3.4b Samples Collected from Monitoring Stations
During August 1999 and September 1999 Trawl Surveys
Which Exceeded the Detection Limit (dl) a |
Contaminants |
August
1999 Trawl Sampling |
September
1999 Trawling Sampling |
(in
Biota) |
No.
(%) of stations above dI |
Futher
analysis |
No.
(%) of stations above dI |
Futher
analysis |
Total
DDT |
52
(87%) |
Graphical
presentation with discussion and statistical analysis |
55
(92%) |
Graphical
presentation with discussion and statistical analysis
|
Total
PCBs |
31
(52%) |
Graphical
presentation with discussion |
30
(50%) |
Graphical
presentation with discussion |
TBT |
2
(3%) |
None |
0
(0%) |
None |
Acenaphthene |
0
(0%) |
None |
0
(0%) |
None |
Acenaphthylene |
0
(0%) |
None |
1
(2%) |
None |
Anthracene |
0
(0%) |
None |
1
(2%) |
None |
Fluorene |
0
(0%) |
None |
2
(3%) |
None |
Naphthalene |
16
(27%) |
Graphical
presentation with discussion |
20
(33%) |
Graphical
presentation with discussion |
Phenanthrene |
0
(0%) |
None |
3
(5%) |
None |
Low
Molecular Weight PAHs |
0
(0%) |
None |
2
(3%) |
None |
Benzo(a)anthracene |
0
(0%) |
None |
8
(13%) |
None |
Benzo(a)pyrene |
0
(0%) |
None |
1
(2%) |
None |
Chrysene |
0
(0%) |
None |
7
(12%) |
None |
Dibenzo(a,h)
- anthracene |
0
(0%) |
None |
1
(2%) |
None |
Fluoranthene |
0
(0%) |
None |
1
(2%) |
None |
Pyrene |
0
(0%) |
None |
0
(0%) |
None |
High
Molecular Weight PAHs |
0
(0%) |
None |
0
(0%) |
None |
Total
PAHs |
0
(0%) |
None |
0
(0%) |
None |
a
- 0% to 15% no presentation, 15% graphical presentation
(with discussion for naphthalene only), > 50% discussion
with graphical presentation and statistical analysis
if detected in greater than 60% of stations
|